CAS: 13035-61-5
MF: C13H18O9
Appearance: white to almost white crystalline powder
Nucleotides: | Precursor in the synthesis of nucleotides, which have antiproliferative activity against cancer cells. |
Nucleosides: | Starting material for the synthesis of nucleosides. |
Ribosylations: | Used in ribosylation reactions. |
Hazards: | Can cause skin and eye irritation, and may irritate the respiratory system. |
Skin Contact: | Wash immediately with soap and water, and remove any contaminated clothing or shoes. |
InChI:InChI=1/C13H18O9/c1-6(14)18-5-10-11(19-7(2)15)12(20-8(3)16)13(22-10)21-9(4)17/h10-13H,5H2,1-4H3/t10-,11?,12?,13-/m1/s1
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The potent and selective antiviral drug ...
Several thio-D-xylose and D-ribose ester...
A series of 1,2,3-triazolyl nucleoside a...
Several glycoconjugates of the diterpeno...
acetic anhydride
G
2,9-diacetylguanine
1,2,3,5-tetraacetylribose
Conditions | Yield |
---|---|
acetic anhydride; G; at 136 ℃; for 1h;
With trifluoroacetic acid; at 60 - 100 ℃;
|
86% 96% |
L-(+)-arabinose
acetic anhydride
1,2,3,6-tetra-O-acetyl-5-deoxy-α-L-arabino-hexofuranose
1,2,3,6-tetra-O-acetyl-5-deoxy-β-L-arabino-hexofuranose
1,2,3,4-tetra-O-acetyl-β-L-arabinopyranose
1,2,3,4-tetra-O-acetyl-α-L-arabinopyranose
Conditions | Yield |
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With pyridine; at 0 ℃; Yield given. Yields of byproduct given;
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With H-Beta zeolite; for 2h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;
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With sodium acetate; Yield given. Yields of byproduct given;
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With pyridine; N,N-dimethyl-formamide; at 120 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
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With sodium acetate; Product distribution; other reagent, other temperature;
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With pyridine; at 25 ℃; for 12h; Reagent/catalyst; Overall yield = 100 %; Overall yield = 11.11 g; stereoselective reaction; Inert atmosphere;
|
20 % de 20 % de |
5-O-triphenylmethyl-D-ribofuranose-1,2,3-triacetate
Acetyl bromide
acetic anhydride
pyridine
4-amino-5-methyl-1-α-D-ribofuranosyl-1H-pyrimidin-2-one
3-β-D-ribofuranosyl-5-(methylthio)-3H-1,2,3-triazolo<4,5-d>pyrimidin-7-amine
(2R,3R,4S,5R)-2-(7-Amino-5-methylsulfanyl-[1,2,3]triazolo[4,5-d]pyrimidin-2-yl)-5-hydroxymethyl-tetrahydro-furan-3,4-diol
(2R,3R,4S,5R)-2-(7-Amino-5-methanesulfonyl-[1,2,3]triazolo[4,5-d]pyrimidin-2-yl)-5-hydroxymethyl-tetrahydro-furan-3,4-diol