CAS: 553-26-4
MF: C10H8N2
Appearance: off-white to tan powder
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4,4′-Bipyridine is a heterocyclic compound consisting of two pyridine rings connected at the para-positions. It is widely utilized as a building block in advanced materials, especially within supramolecular chemistry, where it functions as a bidentate ligand in coordination frameworks like COFs and MOFs due to its electro- and photo-responsive properties. A prominent derivative class, viologens (N,N′-disubstituted 4,4′-bipyridines), exhibit diverse multifunctional characteristics such as electrochromism, making them suitable for high-tech applications including molecular motors, switches, and sensors. Viologens can undergo electron reduction, yielding colorful, stable radical cations with tunable electronic and optical properties based on their substituents and counterions. This tunability extends to various environmental stimuli, positioning viologens and 4,4′-bipyridine derivatives as essential components in developing materials responsive to light, heat, and solvent polarity, with applications in fields like glucose sensing and liquid crystalline systems.
Rate constants for intramolecular electr...
The robust metal−organic framework compound {[Zn2(L)]·4H2O}∞I has been synthesized by hydrothermal reaction of ZnCl2 and 4,4‘-bipyridine-2,6,2‘,6‘-tetracarboxylic acid (H4L). Compound I crystallizes in a chiral space group, P42212, with the chirality generated by the helical chains of hydrogen-bonded guest water molecules rather than by the coordination framework.
Emphasis is placed on solvent-/medium- and environment-responsive 4,4′-bipyridine derivatives. Two important classes of 4,4′-bipyridine-based products with solvatochromic and/or environment-responsive character are reviewed: viologens (i.e., N,N′-disubstituted derivatives) and monoquats (i.e., monosubstituted 4,4′-bipyridine derivatives). The multifunctional nature of these derivatives is analyzed and structure–property relations are discussed in connection to the role of these derivatives in various novel applications.