CAS： 13674-84-5
MF： C9H18Cl3O4P
Appearance： Clear colorless viscous liquid
| Description | Phosphoric acid tris(2-chloro-1-methylethyl) ester (TCIPP) is an emerging contaminant which is ubiquitous in the indoor and outdoor environment. |
| Composition | Mixture of isomers; typical composition includes 66% tris(1-chloro-2-propyl) phosphate with minor isomers like bis(1-chloro-2-propyl) (2-chloropropyl) phosphate. |
| Uses | Flame retardant primarily in polyurethane foams (both rigid and flexible). Identified as a potential endocrine disruptor; under increasing regulatory scrutiny for environmental and health impacts. |
|
Air & Water Reactions |
Insoluble in water. |
|
Reactivity Profile |
Phosphoric acid tris(2-chloro-1-methylethyl) ester may hydrolyze under acidic or alkaline conditions. |
| Ventilation | Use in a well-ventilated area; ensure a safety shower is nearby. |
| Acute/Chronic Hazards: | Emission of toxic fumes upon decomposition when heated. |
InChI:InChI=1/C9H18Cl3O4P/c1-7(4-10)14-17(13,15-8(2)5-11)16-9(3)6-12/h7-9H,4-6H2,1-3H3
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Our data indicate that BCIPP is the major metabolite of TCIPP formed in the liver. To our knowledge, this is the first quantitative assessment of the stability of Phosphoric acid tris(2-chloro-1-methylethyl) ester (TCIPP) in tissues of humans or any other species. Further research is needed to confirm whether these biotransformation reactions are associated with a decrease or increase in toxicity.
The invention describes a process for pr...
methyloxirane
Tris(2-chloropropyl) phosphate
2-methyl-2-pentenal
tris-(2-chloro, 1-methylethyl)-phosphate
bis(2-chloro-1-methylethyl)(2-chloropropyl)phosphate
2-chloro-1-methylethyl bis(2-chloropropyl)phosphate
| Conditions | Yield |
|---|---|
|
With trichlorophosphate; aluminum (III) chloride; at 40 - 65 ℃; for 6h; Product distribution / selectivity;
|
|
|
With trichlorophosphate; titanium tetrachloride; at 40 - 65 ℃; for 6h; Product distribution / selectivity;
|
methyloxirane
Tris(2-chloropropyl) phosphate
tris-(2-chloro, 1-methylethyl)-phosphate
bis(2-chloro-1-methylethyl)(2-chloropropyl)phosphate
2-chloro-1-methylethyl bis(2-chloropropyl)phosphate
| Conditions | Yield |
|---|---|
|
With trichlorophosphate; aluminum (III) chloride; at 50 - 95 ℃; for 6h; Product distribution / selectivity;
|
methyloxirane
LACTIC ACID
propylene glycol
1-hydroxypropan-2-yl dihydrogenphosphate
diisopropylphosphate
