CAS： 123-35-3
MF： C10H16
Appearance： clear to pale yellow liquid
|
Preparation |
From linalool |
|
Definition |
ChEBI: A monoterpene that is octa-1,6-diene bearing methylene and methyl substituents at positions 3 and 7 respectively. |
|
Aroma threshold values |
Aroma characteristics at 10%: terpy, herbaceous, woody with a rosy celery and carrot nuance |
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Taste threshold values |
Taste characteristics at 5 to 100 ppm: woody, vegetative, citrus fruity with a tropical mango and slight, leafy, minty nuance |
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Synthesis Reference(s) |
Journal of the American Chemical Society, 97, p. 3252, 1975 DOI: 10.1021/ja00844a073The Journal of Organic Chemistry, 47, p. 4161, 1982 DOI: 10.1021/jo00142a031Tetrahedron Letters, 25, p. 5193, 1984 DOI: 10.1016/S0040-4039(01)81561-6 |
|
General Description |
A yellow oily liquid with a pleasant odor. Flash point below 200°F. Insoluble in water and less dense than water. |
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Air & Water Reactions |
Insoluble in water. |
|
Reactivity Profile |
The unsaturated aliphatic hydrocarbons, such as MYRCENE, are generally much more reactive than the alkanes. Strong oxidizers may react vigorously with them. Reducing agents can react exothermically to release gaseous hydrogen. In the presence of various catalysts (such as acids) or initiators, compounds in this class can undergo very exothermic addition polymerization reactions. Many of these compounds undergo autoxidation upon exposure to the air to form explosive peroxides. Violent explosions have occurred at low temperatures in ammonia synthesis gas units. These explosions have been traced to the addition products of dienes and oxides of nitrogen, produced from the interaction of nitrogen oxide and oxygen [Bretherick, 1995]. |
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Health Hazard |
May be harmful by inhalation, ingestion or skin absorption. |
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Fire Hazard |
Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flashback. |
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Safety Profile |
Low toxicity by ingestion and skin contact. Experimental reproductive effects. A moderate skin and eye irritant. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes. |
InChI:InChI=1/C10H16/c1-5-10(4)8-6-7-9(2)3/h5,7H,1,4,6,8H2,2-3H3
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styrene
3-methyl-butan-2-one
7-methyl-3-methene-1,6-octadiene
β-thujene
| Conditions | Yield |
|---|---|
|
at 610 ℃;
|
3,7-dimethyl-oct-6-enal
7-methyl-3-methene-1,6-octadiene
1-methyl-4-isopropyl-1,3-cyclohexadiene
3,8-p-Menthadien
3-p-menthene
(+/-)-menthone
| Conditions | Yield |
|---|---|
|
With aluminum oxide; carbon dioxide; In hexane; at 190 ℃; Supercritical conditions;
|
21.4% 6.6% 8.2% 6.9% 6.3% |
linalool
linalool acetate
γ-geraniol
beta-pinene
4-(4-methyl-pent-3-enyl)-cyclohex-4-ene-1,2-dicarboxylic acid
4-(4-methyl-3-pentenyl)-4-cyclohexene-1,2-dicarboxylic acid anhydride
(+/-)-4-(4-methyl-pent-3-enyl)-cyclohex-4-ene-1r,2c-dicarboxylic acid-anhydride
6,7-epoxymyrcene
