CAS: 21806-61-1
MF: C3H4O3S
Prop-1-ene-1,3-sultone (PES) is a versatile chemical compound primarily used as an electrolyte additive in lithium-ion batteries (LIBs), where it enhances performance and longevity. PES helps form a protective solid electrolyte interphase (SEI) on the graphite anode, preventing the co-intercalation of propane carbonate (PC) and reducing gas production during the first charge cycle. It also prevents destructive exfoliation of the anode and acts as a photoelectron sensitizer. PES is soluble in both organic solvents and deionized water, and it is more easily reduced than propane sultone (PS), a similar compound used in LIBs. In addition to its role in battery technology, PES is utilized in asymmetric synthesis as a ligand for transition metal ions, such as Fe2+, and has antioxidant properties. However, PES is hazardous, being toxic, carcinogenic, mutagenic, and teratogenic, with potential for skin absorption, inhalation, or ingestion. It poses environmental risks and should be handled with caution, including the use of personal protective equipment and adherence to safety guidelines.
InChI:InChI=1/C3H4O3S/c4-7(5)3-1-2-6-7/h1,3H,2H2
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Li[Ni1/3Mn1/3Co1/3]O2 (NMC111)/graphite pouch cells made with varying concentrations of the electrolyte additive prop-1-ene-1,3-sultone (PES), were studied using high precision coulometry and storage experiments as well as gas evolution and electrochemical impedance spectroscopy (EIS) measurements. Prop-1-ene-1,3-sultone (PES) was found to have smaller irreversible capacity than VC-containing cells, and was suggested to be a stable SEI forming additive....
The physical and chemical properties of the solid electrolyte interphase (SEI) formed by prop-1-ene-1,3-sultone (PES) on graphite anode in propylene carbonate (PC) based electrolyte for lithium ion battery were investigated by charge–discharge test, scanning electron spectroscopy with energy dispersive X-ray spectroscopy (SEM–EDS),...
1-hydroxyprop-2-ene-3-sulfonic acid
1-propenyl-1,3-sulfonic acid lactone
Conditions | Yield |
---|---|
With 4-methoxy-phenol; at 135 ℃; for 1h; under 2 Torr;
|
79% |
With pyridinium p-toluenesulfonate; at 100 ℃; under 5 Torr; Pressure; Reagent/catalyst; Temperature; Green chemistry;
|
66% |
at 20 - 110 ℃; under 2.25023 Torr; Temperature;
|
64% |
at 130 - 145 ℃;
|
12 g |
2-hydroxy-1,3-propanesultone
1-propenyl-1,3-sulfonic acid lactone
Conditions | Yield |
---|---|
With methanesulfonyl chloride; triethylamine; In ethyl acetate; at -20 - 10 ℃; for 4h; Cooling with ice;
|
94% |
2-bromopropane-1,3-sultone
Oxiranyl-methanesulfonyl chloride
allyl ethenesulfonate
1-hydroxyprop-2-ene-3-sulfonic acid
(+/-)-7-methyl-3a,4,7,7a-tetrahydro-2,1-oxathiaindene 1,1-dioxide
2-((S)-1-Phenyl-ethyl)-2,3-dihydro-isothiazole 1,1-dioxide